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Carbon-14 dating has an interesting limitation in that the ratio of regular carbon to carbon-14 in the air is not constant and therefore any date must be calibrated using dendrochronology.Symbolically, the process of radioactive decay can be expressed by the following differential equation, where N is the quantity of decaying nuclei and k is a positive number called the exponential decay constant.The meaning of this equation is that the rate of change of the number of nuclei over time is proportional only to the number of nuclei.It suffers from the problem that rubidium and strontium are very mobile and may easily enter rocks at a much later date to that of formation.This method for rock dating is based on the decay of potassium-40 into argon: until the rock solidifies, argon can escape, so it can in theory date the formation of rock.

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